Melting temperature elevation of benzene confined in graphitic micropores

被引：93

作者：

Watanabe, A ^{[1
]}

Iiyama, T ^{[1
]}

Kaneko, K ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Sci & Technol, Chiba 2638522, Japan

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 305卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(99)00362-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Melting and freezing behaviors of benzene confined in graphitic micropores of different pore widths were examined by the use of differential scanning calorimetry (DSC) over the temperature range of 180-320 K. A single diffuse DSC peak due to melting was observed for confined benzene above the melting temperature of bulk benzene. The melting temperature of confined benzene was in the range of 294-298 K, which is higher than that of bulk benzene by 16-20 K. The observed enthalpy of fusion of confined benzene was in the range of 4-5 J mol(-1), which is much smaller than that of bulk benzene (10.7 kJ mol(-1)). (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：71 / 74

页数：4

共 24 条

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