H2S sensitivity study of polypyrrole/WO3 materials

被引:49
作者
Geng, Lina [1 ]
Huang, Xueliang [1 ]
Zhao, Yingqiang [1 ]
Li, Peng [1 ]
Wang, Shurong [1 ]
Zhang, Shoumin [1 ]
Wu, Shihua [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
H2S; gas sensitivity; polypyrrole; WO3;
D O I
10.1016/j.sse.2006.04.024
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this work, a H2S sensor formed from hybrid of WO3 and polypyrrole (PPy) by mechanical mixing was produced. The gas-sensing properties of the hybrid materials were studied and compared with those of PPy and WO3. It was found that PPY/WO3 materials can complement the drawbacks of pure PPy and WO3 to Some extent. PPY/WO3 materials with varies PPy mass percent (1%, 3%, 5%, 10%, 20%) had better reversibility than PPy, and also had higher sensitivity than WO3 when operated at 90 degrees C. The sensing mechanism of PPy/WO3 materials to H2S was presumed to be the synergism of PPy and WO3 or the effect of p-n heterojunctions. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:723 / 726
页数:4
相关论文
共 21 条
[1]   POLYANILINE THIN-FILMS FOR GAS-SENSING [J].
AGBOR, NE ;
PETTY, MC ;
MONKMAN, AP .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 28 (03) :173-179
[2]   Hydrogen sulfide sensing characteristics of tin oxide sol-derived thin films [J].
Ando, M ;
Suto, S ;
Suzuki, T ;
Tsuchida, T ;
Nakayama, C ;
Miura, N ;
Yamazoe, N .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1996, 104 (05) :409-414
[3]  
[Anonymous], SENSORS ACTUATORS B
[4]   THE MECHANISM OF OPERATION OF WO3-BASED H2S SENSORS [J].
BARRETT, EPS ;
GEORGIADES, GC ;
SERMON, PA .
SENSORS AND ACTUATORS B-CHEMICAL, 1990, 1 (1-6) :116-120
[5]   Hybrid organic-inorganic sensors [J].
Bescher, E ;
Mackenzie, JD .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 1998, 6 (2-3) :145-154
[6]  
Costello BPJD, 1996, J MATER CHEM, V6, P289
[7]  
Geng LN, 2005, CHINESE J INORG CHEM, V21, P977
[8]  
GENG LN, IN PRESS MAT CHEM PH
[9]  
HE TP, 1997, CHIN J SYNTH CHEM, V5, P4
[10]   Synthesis of polypyrrole/MoO3 hybrid thin films and their volatile organic compound gas-sensing properties [J].
Hosono, K ;
Matsubara, I ;
Murayama, N ;
Woosuck, S ;
Izu, N .
CHEMISTRY OF MATERIALS, 2005, 17 (02) :349-354