H2S sensitivity study of polypyrrole/WO3 materials

被引:49
作者
Geng, Lina [1 ]
Huang, Xueliang [1 ]
Zhao, Yingqiang [1 ]
Li, Peng [1 ]
Wang, Shurong [1 ]
Zhang, Shoumin [1 ]
Wu, Shihua [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
H2S; gas sensitivity; polypyrrole; WO3;
D O I
10.1016/j.sse.2006.04.024
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this work, a H2S sensor formed from hybrid of WO3 and polypyrrole (PPy) by mechanical mixing was produced. The gas-sensing properties of the hybrid materials were studied and compared with those of PPy and WO3. It was found that PPY/WO3 materials can complement the drawbacks of pure PPy and WO3 to Some extent. PPY/WO3 materials with varies PPy mass percent (1%, 3%, 5%, 10%, 20%) had better reversibility than PPy, and also had higher sensitivity than WO3 when operated at 90 degrees C. The sensing mechanism of PPy/WO3 materials to H2S was presumed to be the synergism of PPy and WO3 or the effect of p-n heterojunctions. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:723 / 726
页数:4
相关论文
共 21 条
[21]  
XU JQ, 2002, CHIN J FUNCT MAT, V33, P33