Biomimetic synthesis of gold nanocrystals using a reducing amphiphile

被引：22

作者：

Gonzaga, Ferdinand ^{[1
]}

Singh, Sherdeep ^{[1
]}

Brook, Michael A. ^{[1
]}

机构：

[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada

来源：

SMALL | 2008年 / 4卷 / 09期

基金：

加拿大自然科学与工程研究理事会;

关键词：

biomimetic synthesis; crystal growth; gold; self-assembly; surfactants;

D O I：

10.1002/smll.200701163

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first synthesis of a chelating and reactive surfactant derived from citric acid and a short silicone as hydrophobic tail is described. Aqueous solutions of this reactive amphiphile spontaneously induce gold ion reduction, particle nucleation, and further direct crystal growth. The process, both pH and light dependent, occurs through lipid-directed assembly of metal ions, their reduction and subsequent lipid-directed growth to yield ultrathin (approximately 7nm thick) quasi two-dimensional gold nanocrystals.

引用

页码：1390 / 1398

页数：9

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