Poisoning of SOFC anodes by various fuel impurities

被引：198

作者：

Haga, K. ^{[1
]}

Adachi, S. ^{[2
]}

Shiratori, Y. ^{[1
]}

Itoh, K. ^{[1
]}

Sasaki, K. ^{[1
,2
,3
]}

机构：

[1] Kyushu Univ, Fac Engn, Nishi Ku, Fukuoka 8190395, Japan

[2] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Fukuoka 8190395, Japan

[3] Kyushu Univ, Hydrogen Technol Res Ctr, Nishi Ku, Fukuoka 8190395, Japan

来源：

SOLID STATE IONICS | 2008年 / 179卷 / 27-32期

关键词：

solid oxide fuel cell; anodes; poisoning; fuel impurity; durability;

D O I：

10.1016/j.ssi.2008.02.062

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Poisoning effects by various fuel impurities, including H2S, CH3SH, COS, Cl-2, and siloxane, to Ni-ScSZ cermet anodes have been analyzed and compared. Degradation of cell performance caused by these impurities was characterized by measuring cell voltage and anode polarization at a constant current density of 0.2 Acm(-2) for humidified H-2 and CH4 fuels. Poisoning for hydrogen-based fuels containing 5 ppm sulfur compounds, H2S, CH3SH, and COS, caused an initial cell voltage drop of about 15 mV at 1000 degrees C. The initial voltage drop was independent of the kind of sulfur compounds, whereas in the case of poisoning by CH3SH, an additional gradual decrease in cell voltage was clearly detected after the initial voltage drop. Thermochemical calculation and FESEM-EDX analysis also indicated that the poisoning by Cl-2 caused the fon-nation of nickel nano-particles on zirconia grains via NiCl2 (g), while the poisoning by siloxane formed segregated silica (SiO2) in porous cermet anodes. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1427 / 1431

页数：5

共 8 条

[1] A solid oxide fuel cell operating on hydrogen sulfide (H2S) and sulfur-containing fuels
Aguilar, L
Zha, SW
Cheng, Z
Winnick, J
Liu, ML
[J]. JOURNAL OF POWER SOURCES, 2004, 135 (1-2) : 17 - 24
[2] Catalytic upgrading of tarry fuel gases: A kinetic study with model components
Jess, A
[J]. CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 1996, 35 (06) : 487 - 494
[3] Larminie J., 2003, FUEL CELL SYSTEMS EX
[4] The poisoning effect of sulfur-containing impurity gas on a SOFC anode: Part I. Dependence on temperature, time, and impurity concentration
Matsuzaki, Y
Yasuda, I
[J]. SOLID STATE IONICS, 2000, 132 (3-4) : 261 - 269
[5] Fuel Impurity Tolerance of Solid Oxide Fuel Cells
Sasaki, K.
Adachi, S.
Haga, K.
Uchikawa, M.
Yamamoto, J.
Iyoshi, A.
Chou, J. -T.
Shiratori, Y.
Itoh, K.
[J]. SOLID OXIDE FUEL CELLS 10 (SOFC-X), PTS 1 AND 2, 2007, 7 (01): : 1675 - 1683
[6] H2S poisoning of solid oxide fuel cells
Sasaki, K.
Susuki, K.
Iyoshi, A.
Uchimura, M.
Imamura, N.
Kusaba, H.
Teraoka, Y.
Fuchino, H.
Tsujimoto, K.
Uchida, Y.
Jingo, N.
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (11) : A2023 - A2029
[7] Equilibria in fuel cell gases - II. The C-H-O ternary diagrams
Sasaki, K
Teraoka, Y
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (07) : A885 - A888
[8] Effects of coal syngas and H2S on the performance of solid oxide fuel cells:: Single-cell tests
Trembly, Jason P.
Marquez, Andres I.
Ohrn, Ted R.
Bayless, David J.
[J]. JOURNAL OF POWER SOURCES, 2006, 158 (01) : 263 - 273

← 1 →