Solubilities of hydrogen in aromatic hydrocarbons from 323 to 433 K and pressures to 21.7 MPa

被引：48

作者：

Park, J ^{[1
]}

Robinson, RL ^{[1
]}

Gasem, KAM ^{[1
]}

机构：

[1] OKLAHOMA STATE UNIV,SCH CHEM ENGN,STILLWATER,OK 74078

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1996年 / 41卷 / 01期

关键词：

D O I：

10.1021/je950152n

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The solubilities of hydrogen in benzene, naphthalene, phenanthrene, and pyrene were measured using a static equilibrium cell over the temperature range from 323.2 to 433.2 K and pressures to 21.7 MPa. The uncertainty in these new solubility measurements is estimated to be less than 0.001 in mole fraction. The data were analyzed using the Soave-Redlich-Kwong (SRK) and Peng-Robinson (PR) equations of state (EOS). In general, the two equations represent the experimental data well when a single interaction parameter (C-ij) is used for each isotherm. The data suggest that the EOS C-ij interaction parameter is highly temperature dependent.

引用

页码：70 / 73

页数：4

共 20 条

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