Surface rearrangement of diblock copolymer brushes - Stimuli responsive films

被引：76

作者：

Brittain, William J. ^{[1
]}

Boyes, Stephen G.

Granville, Anthony M.

Baum, Marina

Mirous, Brian K.

Akgun, Bulent

Zhao, Bin

Blickle, Carl

Foster, Mark D.

机构：

[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA

[2] Univ So Mississippi, Dept Polymer Sci, Hattiesburg, MS 39406 USA

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

SURFACE- INITIATED POLYMERIZATION II | 2006年 / 198卷 / 125-147期

关键词：

ATRP; block copolymers; polymer brushes; stimuli-responsive; thin films;

D O I：

10.1007/12_061

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This article reviews results from our group of the synthesis and characterization of diblock copolymer brushes. Results from the literature are also covered. We report a wide variety of diblock compositions and compare the miscibility of the two blocks with the tendency to rearrange in response to block-selective solvents. Also, we describe the types of polymerization methods that can be utilized to prepare diblock copolymer brushes. We have compared the molecular weight of free polymer and the polymer brush based on results from our laboratory and other research groups; we have concluded that the molecular weight of the free polymer and that of degrafted polymer brushes is similar.

引用

页码：125 / 147

页数：23

共 69 条

[1] Polymer brushes by living anionic surface initiated polymerization on flat silicon (SiOx) and gold surfaces:: Homopolymers and block copolymers [J].

Advincula, R ;

Zhou, QG ;

Park, M ;

Wang, SG ;

Mays, J ;

Sakellariou, G ;

Pispas, S ;

Hadjichristidis, N .

LANGMUIR, 2002, 18 (22) :8672-8684

[2]

Advincula R.C., 2004, POLYM BRUSHES

[3] Synthesis of polymer brushes on silicate substrates via reversible addition fragmentation chain transfer technique [J].

Baum, M ;

Brittain, WJ .

MACROMOLECULES, 2002, 35 (03) :610-615

[4]

BAUM M, 2002, THESIS U AKRON

[5] Developments in CO2 research [J].

Behles, JA ;

DeSimone, JM .

PURE AND APPLIED CHEMISTRY, 2001, 73 (08) :1281-1285

[6] Synthesis, characterization, and properties of polyelectrolyte block copolymer brushes prepared by atom transfer radical polymerization and their use in the synthesis of metal nanoparticles [J].

Boyes, SG ;

Akgun, B ;

Brittain, WJ ;

Foster, MD .

MACROMOLECULES, 2003, 36 (25) :9539-9548

[7] Synthesis, characterization, and properties of ABA type triblock copolymer brushes of styrene and methyl acrylate prepared by atom transfer radical polymerization [J].

Boyes, SG ;

Brittain, WJ ;

Weng, X ;

Cheng, SZD .

MACROMOLECULES, 2002, 35 (13) :4960-4967

[8] Golden interfaces: The surface of self-assembled monolayers [J].

Delamarche, E ;

Michel, B ;

Biebuyck, HA ;

Gerber, C .

ADVANCED MATERIALS, 1996, 8 (09) :719-&

[9] Controlled grafting of N-isoproply acrylamide brushes onto self-standing isotactic polypropylene thin films:: surface initiated atom transfer radical polymerization [J].

Desai, SM ;

Solanky, SS ;

Mandale, AB ;

Rathore, K ;

Singh, RP .

POLYMER, 2003, 44 (25) :7645-7649

[10] PHASE-SEPARATION OF GRAFTED COPOLYMERS [J].

DONG, H ;

MARKO, JF ;

WITTEN, TA .

MACROMOLECULES, 1994, 27 (22) :6428-6442

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