Boronic ester as a linker system for solid phase synthesis

被引:47
作者
Carboni, B [1 ]
Pourbaix, C [1 ]
Carreaux, F [1 ]
Deleuze, H [1 ]
Maillard, B [1 ]
机构
[1] Univ Rennes 1, CNRS, UMR, F-35042 Rennes, France
关键词
D O I
10.1016/S0040-4039(99)01649-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A method for attaching boronic acids to a macroporous polymer-supported 1,3-diol was developed. Chemical modifications of some polymer-bound arylboronic acids were realised using various reaction conditions. Transesterification gave new boronates in high purity while oxidative cleavage directly led to phenols. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码:7979 / 7983
页数:5
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