Cyclohexane selective oxidation over metal-organic frameworks of MIL-101 family: superior catalytic activity and selectivity

被引：180

作者：

Maksimchuk, Nataliya V. ^{[1
]}

Kovalenko, Konstantin A. ^{[2
,3
]}

Fedin, Vladimir P. ^{[2
,3
]}

Kholdeeva, Oxana A. ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

[2] Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[3] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 54期

关键词：

LIQUID-PHASE OXIDATION; MOLECULAR-SIEVE CATALYSTS; AEROBIC OXIDATION; ALUMINOPHOSPHATE-5; DECOMPOSITION; CO-TUD-1;

D O I：

10.1039/c2cc31877f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mesoporous metal-organic frameworks Cr- and Fe-MIL-101 are highly efficient, true heterogeneous and recyclable catalysts for solvent-free selective oxidation of cyclohexane with molecular oxygen and/or tert-butyl hydroperoxide under mild conditions.

引用

页码：6812 / 6814

页数：3

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