Utilising matrix-assisted laser desorption/ionisation techniques for the generation of structural information from different end-group functionalised poly(methyl methacrylate)s

被引：14

作者：

Jackson, Anthony T. ^{[1
]}

Bunn, Alan ^{[2
]}

Chisholm, Michael S. ^{[3
]}

机构：

[1] AkzoNobel CARG, Shanghai 201600, Peoples R China

[2] ICI Plc, Wilton Ctr, ICI Measurement Sci Grp, Redcar TS10 4RF, Cleveland, England

[3] Lucite Int UK Ltd, Wilton Ctr, Shanghai 201600, Peoples R China

来源：

POLYMER | 2008年 / 49卷 / 24期

关键词：

MALDI; MS/MS; PMMA;

D O I：

10.1016/j.polymer.2008.09.051

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

End-group characterisation of three functionalised poly(methyl methacrylate) (PMMA) samples was performed by means of matrix-assisted laser desorption/ionisation-mass spectrometry (MALDI-MS). MALDI-time of flight (MALDI-TOF) data were employed to generate information about the initiators and chain-transfer agents used for the polymerisations. Further confirmation of the structural assignments was gleaned from MALDI-collision-induced dissociation (MALDI-CID) experiments. This latter technique is a powerful method for generating information on the masses of individual end groups. (c) 2008 Elsevier Ltd. All rights reserved.

引用

收藏

页码：5254 / 5261

页数：8

相关论文

共 55 条

[1] Probing mechanistic features of conventional, catalytic and living free radical polymerizations using soft ionization mass spectrometric techniques [J].

Barner-Kowollik, C ;

Davis, TP ;

Stenzel, MH .

POLYMER, 2004, 45 (23) :7791-7805

[2]

BARSON CA, 1989, COMPREHENSIVE POLYM, V3, P171

[3] A COMBINED MAGNETIC SECTOR-TIME-OF-FLIGHT MASS-SPECTROMETER FOR STRUCTURAL DETERMINATION STUDIES BY TANDEM MASS-SPECTROMETRY [J].

BATEMAN, RH ;

GREEN, MR ;

SCOTT, G ;

CLAYTON, E .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1995, 9 (13) :1227-1233

[4] Degradation of poly(methyl methacrylate) model compounds at constant elevated temperature studied via high resolution electrospray ionization mass spectrometry (ESI-MS) [J].

Bennet, Francesca ;

Lovestead, Tara M. ;

Barker, Philip J. ;

Davis, Thomas P. ;

Stenzel, Martina H. ;

Barner-Kowollik, Christopher .

MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (16) :1593-1600

[5] Evidence for the low thermal stability of poly(methyl methacrylate) polymer produced by atom transfer radical polymerisation [J].

Borman, CD ;

Jackson, AT ;

Bunn, A ;

Cutter, AL ;

Irvine, DJ .

POLYMER, 2000, 41 (15) :6015-6020

[6] Characterization of linear and branched polyacrylates by tandem mass spectrometry [J].

Chaicharoen, Kittisak ;

Polce, Michael J. ;

Singh, Anirudha ;

Pugh, Coleen ;

Wesdemiotis, Chrys .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2008, 392 (04) :595-607

[7] NMR-STUDIES OF POLYMERIC MATERIALS - AN OVERVIEW [J].

CHENG, HN ;

EARLY, TA .

MACROMOLECULAR SYMPOSIA, 1994, 86 :1-14

[8] Binary copolymerization with catalytic chain transfer. A method for synthesizing macromonomers based on monosubstituted monomers [J].

Chiefari, J ;

Jeffery, J ;

Krstina, J ;

Moad, CL ;

Moad, G ;

Postma, A ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 2005, 38 (22) :9037-9054

[9]

DAVIS TP, 1995, TRENDS POLYM SCI, V3, P365

[10] Conventional and catalytic chain transfer in the free-radical polymerization of 2-phenoxyethyl methacrylate [J].

Forster, DJ ;

Heuts, JPA ;

Davis, TP .

POLYMER, 2000, 41 (04) :1385-1390

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