1,3,5-triazine templated self-assembly of a hexameric copper(I) chloride triphenyl phosphite core

被引：38

作者：

Pike, RD ^{[1
]}

Borne, BD

Maeyer, JT

Rheingold, AL

机构：

[1] Coll William & Mary, Dept Chem, Williamsburg, VA 23187 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 04期

关键词：

D O I：

10.1021/ic015605q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CuCl, P(OPh)3, and 1,3,5-triazine (Trz) in CHCl3 produces [(CuCl)(6)(P(OPh)(3))(6)(TrZ)(2)] via molecular self-assembly. An X-ray structural study has revealed a D-3d symmetry hexamer containing an oblate spheroid core. The core consists of a Cu6Cl6 macrocycle, which is capped by two mu(3)-Trz ligands. Seven parallel stacked atom planes are present P-3, Trz, Cu-3, Cl-6, Cu-3, Trz, and P-3. The six copper atoms are not coplanar with the Trz ligands and form a distorted octahedron. Crystal data: triclinic P (1) over bar, a 14.1489(7) Angstrom, b = 15.7470(8) Angstrom, c 29.6572(14) Angstrom, alpha 76.4330(10)degrees, beta = 79.5120(10)degrees, gamma = 72 2260(10)degrees, V = 6088.5(5) Angstrom(3), Z = 2, 27470 reflections, R = 0.0359.

引用

页码：631 / 633

页数：3

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