Copper(I) halide supramolecular networks linked by N-heterocyclic donor bridging ligands

被引：112

作者：

Blake, AJ ^{[1
]}

Brooks, NR ^{[1
]}

Champness, NR ^{[1
]}

Hanton, LR ^{[1
]}

Hubberstey, P ^{[1
]}

Schröder, M ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

PURE AND APPLIED CHEMISTRY | 1998年 / 70卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1351/pac199870122351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We are pursuing the construction of extended supramolecular networks based upon inorganic co-ordination polymers using a building block methodology to control network structure. We have been attracted by the rich structural chemistry of copper(I) halides and pseudo-halides in order to form neutral networks with N-heterocyclic donor bridging ligands. By using the potentially tridentate ligand, 1,3,5-triazine, three-dimensional supramolecular networks containing unusual columnar (CuX)(infinity) or sheet (CuI)(infinity) motifs can be prepared. With bidentate bridging ligands, [Cu(SCN)](infinity) sheet motifs have been obtained.

引用

页码：2351 / 2357

页数：7

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