Loading of Two Related Metal-Organic Frameworks (MOFs), [Cu2(bdc)2(dabco)] and [Cu2(ndc)2(dabco)], with Ferrocene

被引：24

作者：

Heck, Romain ^{[1
]}

Shekhah, Osama ^{[1
]}

Zybaylo, Olexandra ^{[1
]}

Weidler, Peter G. ^{[1
]}

Friedrich, Frank ^{[1
]}

Maul, Robert ^{[2
,3
]}

Wenzel, Wolfgang ^{[4
]}

Woell, Christof ^{[1
]}

机构：

[1] Karlsruher Inst Technol, Inst Funkt Grenzflachen, D-76344 Eggenstein Leopoldshafen, Germany

[2] Karlsruher Inst Technol, Steinbuch Ctr Comp, D-76021 Karlsruhe, Germany

[3] Karlsruher Inst Technol, DFG Ctr Funct Nanostruct, D-76021 Karlsruhe, Germany

[4] Karlsruher Inst Technol, Inst Nanotechnol INT, D-76021 Karlsruhe, Germany

来源：

POLYMERS | 2011年 / 3卷 / 03期

关键词：

ferrocene; loading; MOFs;

D O I：

10.3390/polym3031565

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We have studied the loading of two related, similar porous metal-organic frameworks (MOFs) [Cu-2(bdc)(2)(dabco)] (1), and [Cu-2(ndc)(2)(dabco)] (2) with ferrocene by exposing bulk powder samples to the corresponding vapor. On the basis of powder X-ray diffraction data and molecular dynamics (MD) calculations we propose that each pore can store one ferrocene molecule. Despite the rather pronounced similarity of the two MOFs a quite different behavior is observed, for 1 loading with ferrocene leads to an anisotropic 1% contraction, whereas for 2 no deformation is observed. Mossbauer spectroscopy studies reveal that the Fe oxidation level remains unchanged during the process. Time dependent studies reveal that the diffusion constant governing the loading from the gas-phase for 1 is approximately three times larger than the value for 2.

引用

页码：1565 / 1574

页数：10

共 13 条

[1] Adsorption properties of HKUST-1 toward hydrogen and other small molecules monitored by IR [J].

Bordiga, S. ;

Regli, L. ;

Bonino, F. ;

Groppo, E. ;

Lamberti, C. ;

Xiao, B. ;

Wheatley, P. S. ;

Morris, R. E. ;

Zecchina, A. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (21) :2676-2685

[2] The Amber biomolecular simulation programs [J].

Case, DA ;

Cheatham, TE ;

Darden, T ;

Gohlke, H ;

Luo, R ;

Merz, KM ;

Onufriev, A ;

Simmerling, C ;

Wang, B ;

Woods, RJ .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 2005, 26 (16) :1668-1688

[3]

CLARK SJ, 1989, SPEC PR SPR, V22, P363

[4] Rigid and flexible: A highly porous metal-organic framework with unusual guest-dependent dynamic behavior [J].

Dybtsev, DN ;

Chun, H ;

Kim, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) :5033-5036

[5] Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core-Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship [J].

Furukawa, Shuhei ;

Hirai, Kenji ;

Nakagawa, Keiji ;

Takashima, Yohei ;

Matsuda, Ryotaro ;

Tsuruoka, Takaaki ;

Kondo, Mio ;

Haruki, Rie ;

Tanaka, Daisuke ;

Sakamoto, Hirotoshi ;

Shimomura, Satoru ;

Sakata, Osami ;

Kitagawa, Susumu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (10) :1766-1770

[6]

Jost W., 1972, DIFFUSION METHODEN M, P327

[7] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[8] Potential applications of metal-organic frameworks [J].

Kuppler, Ryan J. ;

Timmons, Daren J. ;

Fang, Qian-Rong ;

Li, Jian-Rong ;

Makal, Trevor A. ;

Young, Mark D. ;

Yuan, Daqiang ;

Zhao, Dan ;

Zhuang, Wenjuan ;

Zhou, Hong-Cai .

COORDINATION CHEMISTRY REVIEWS, 2009, 253 (23-24) :3042-3066

[9] Incorporation of metallocenes into the channel structured Metal-Organic Frameworks MIL-53(Al) and MIL-47(V) [J].

Meilikhov, Mikhail ;

Yusenko, Kirill ;

Fischer, Roland A. .

DALTON TRANSACTIONS, 2010, 39 (45) :10990-10999

[10] Reduction of a Metal Organic Framework by an Organometallic Complex: Magnetic Properties and Structure of the Inclusion Compound [(η5-C5H5)2Co]0.5@MIL-47(V) [J].

Meilikhov, Mikhail ;

Yusenko, Kirill ;

Torrisi, Antonio ;

Jee, Bettina ;

Mellot-Draznieks, Caroline ;

Poeppl, Andreas ;

Fischer, Roland A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (35) :6212-6215

← 1 2 →