Epitaxial phase stabilisation phenomena in rare earth manganites

被引：49

作者：

Bosak, AA ^{[1
]}

Kamenev, AA

Graboy, IE

Antonov, SV

Gorbenko, OY

Kaul, AR

Dubourdieu, C

Senateur, JP

Svechnikov, VL

Zandbergen, HW

Holländer, B

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Inst Natl Polytech Grenoble, Mat & Genie Phys Lab, F-38402 St Martin Dheres, France

[3] Delft Univ Technol, Mat Sci Lab, Natl Ctr HREM, NL-2628 AL Delft, Netherlands

[4] Forschungszentrum Julich, ISG1, D-52425 Julich, Germany

来源：

THIN SOLID FILMS | 2001年 / 400卷 / 1-2期

关键词：

rare-earth manganites; thin films; epitaxial stabilisation; metal-organic chemical vapour deposition (MOCVD);

D O I：

10.1016/S0040-6090(01)01501-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Using injection, powder-flash and band-flash MOCVD techniques, epitaxial thin films of Nd, Ho, Y, Tint, Dy and Lu manganites were prepared. The formation of high-pressure phase NdMn(7)O(12) as a thin surface layer on Pnma Nd(1-x)MnO(3+delta) (x similar to0.15) in an Nd-deficient system and HoMnO(3), YMnO(3), TmMnO(3) and LuMnO(3) as perovskite phases (known in the bulk only as high-pressure phases) on a LaAlO(3) substrate were observed. The remarkable reduction in the pressure needed for formation of the phases in epitaxial films in comparison with bulk samples is a manifestation of the epitaxial stabilisation discussed in the paper. The details of the crystal and domain structure of the films as observed by X-ray diffraction (XRD), selected-area electron diffraction (SAED) and high-resolution electron microscopy (HREM) techniques are described. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：149 / 153

页数：5

共 15 条

[1]

BERTAUT F, 1963, CR HEBD ACAD SCI, V257, P867

[2] HIGH-PRESSURE SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW SERIES OF PEROVSKITE-LIKE COMPOUNDS CMN7O12(C = NA, CA, CD, SR, LA, ND) [J].

BOCHU, B ;

CHENAVAS, J ;

JOUBERT, JC ;

MAREZIO, M .

JOURNAL OF SOLID STATE CHEMISTRY, 1974, 11 (02) :88-93

[3] Synthesis of metastable perovskite-type YMnO3 and HoMnO3 [J].

Brinks, HW ;

Fjellvag, H ;

Kjekshus, A .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 129 (02) :334-340

[4] CLASSIFICATION OF TILTED OCTAHEDRA IN PEROVSKITES [J].

GLAZER, AM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1972, B 28 (NOV15) :3384-&

[5]

Kaul AR, 2000, SCHR FZ JUL ENERG, V15, P669

[6] NEW PRINCIPLE OF FEEDING FOR FLASH EVAPORATION MOCVD DEVICES [J].

KAUL, AR ;

SELEZNEV, BV .

JOURNAL DE PHYSIQUE IV, 1993, 3 (C3) :375-378

[7]

KAUL AR, 2000, THIN FILM DEPOSITION, P23

[8] Perovskite rare-earth nickelates in the thin-film epitaxial state [J].

Novojilov, MA ;

Gorbenko, OY ;

Graboy, IE ;

Kaul, AR ;

Zandbergen, HW ;

Babushkina, NA ;

Belova, LM .

APPLIED PHYSICS LETTERS, 2000, 76 (15) :2041-2043

[9] Secondary phases in (001)RBa2Cu3O7-δ epitaxial thin films [J].

Samoylenkov, SV ;

Gorbenko, OY ;

Graboy, IE ;

Kaul, AR ;

Zandbergen, HW ;

Connolly, E .

CHEMISTRY OF MATERIALS, 1999, 11 (09) :2417-2428

[10]

Sénateur JP, 2000, ADV MATER OPT ELECTR, V10, P155, DOI 10.1002/1099-0712(200005/10)10:3/5<155::AID-AMO406>3.0.CO

← 1 2 →