Pentamethylcyclopentadienyl ruthenium: an efficient catalyst for the redox isomerization of functionalized allylic alcohols into carbonyl compounds

被引：51

作者：

Bouziane, Asmae ^{[1
]}

Carboni, Bertrand ^{[1
]}

Bruneau, Christian ^{[1
]}

Carreaux, Francois ^{[1
]}

Renaud, Jean-Luc ^{[2
,3
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France

[2] Ecole Natl Super Chim Rennes, UMR 6226, F-35700 Rennes, France

[3] Univ Caen, ENSICAEN, Lab Chim Mol & Thioorgan, UMR 6507,INC3M,FR 3038, F-14050 Caen, France

来源：

TETRAHEDRON | 2008年 / 64卷 / 51期

关键词：

Ruthenium; Allylic alcohol; Isomerization;

D O I：

10.1016/j.tet.2008.09.095

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

The catalytic activity of the ruthenium(II) complex [RuCp(CH3CN)(3)][PF6] 1 in the transposition of allylic alcohols into carbonyl Compounds, in acetonitrile, is reported. This catalyst has proven to be able to catalyze the transformation of poorly reactive and/or functionalized substrates under smooth conditions. (C) 2008 Published by Elsevier Ltd.

引用

页码：11745 / 11750

页数：6

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