Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV):: a highly efficient catalyst for the isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media

被引：76

作者：

Cadierno, V ^{[1
]}

García-Garrido, SE ^{[1
]}

Gimeno, J ^{[1
]}

机构：

[1] Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan,Unidad Asociada, Inst Univ Quim Organomet Enrique Moles,CSIC, E-33071 Oviedo, Spain

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 02期

关键词：

D O I：

10.1039/b313069j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic activity of the bis(allyl)-ruthenium(IV) complex [Ru(eta(3):eta(2):eta(3)-C12H18)Cl-2] in the transposition of allylic alcohols into carbonyl compounds, both in THF and H2O as solvent, is reported.

引用

页码：232 / 233

页数：2

共 17 条

[1] RHODIUM(I)-CATALYZED BIPHASIC ISOMERIZATION OF ALLYLIC ALCOHOLS [J].

ALPER, H ;

HACHEM, K .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (11) :2269-2270

[2] RUTHENIUM-CATALYZED ISOMERIZATION OF ALLYLIC ALCOHOLS TO SATURATED KETONES [J].

BACKVALL, JE ;

ANDREASSON, U .

TETRAHEDRON LETTERS, 1993, 34 (34) :5459-5462

[3] Isomerization of allylic alcohols to carbonyl compounds by aqueous-biphase rhodium catalysis [J].

Bianchini, C ;

Meli, A ;

Oberhauser, W .

NEW JOURNAL OF CHEMISTRY, 2001, 25 (01) :11-12

[4] Efficient catalytic isomerization of allylic alcohols to carbonyl compounds with water soluble rhodium complexes [J].

de Bellefon, C ;

Caravieilhes, S ;

Kuntz, EG .

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 2000, 3 (07) :607-614

[5] Rhodium catalyzed allylic isomerization in water [J].

Knight, DA ;

Schull, TL .

SYNTHETIC COMMUNICATIONS, 2003, 33 (05) :827-831

[6]

LYDON JE, 1964, P CHEM SOC LONDON, P421

[7] THE MECHANISM OF AQUEOUS RUTHENIUM(II)-CATALYZED OLEFIN ISOMERIZATION [J].

MCGRATH, DV ;

GRUBBS, RH .

ORGANOMETALLICS, 1994, 13 (01) :224-235

[8] AQUEOUS RUTHENIUM(II) COMPLEXES OF FUNCTIONALIZED OLEFINS - THE X-RAY STRUCTURE OF RU(H2O)2(ETA-1(O) - ETA-2(C,C')-OCOCH2CH=CHCH3)2 [J].

MCGRATH, DV ;

GRUBBS, RH ;

ZILLER, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) :3611-3613

[9] TRANSITION-METAL-CARBON BONDS .6. FORMATION OF DICHLORO-(DODECA-2,6,10-TRIENE-1,12-DIYL)RUTHENIUM(4) FROM BUTADIENE AND RUTHENIUM TRICHLORIDE [J].

NICHOLSON, JK ;

SHAW, BL .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (06) :807-+

[10] Improved efficiency of the ruthenium-catalyzed redox isomerization of allyl alcohols [J].

Slugovc, C ;

Rüba, E ;

Schmid, R ;

Kirchner, K .

ORGANOMETALLICS, 1999, 18 (20) :4230-4233

← 1 2 →