Rhodium catalyzed allylic isomerization in water

被引：26

作者：

Knight, DA

Schull, TL

机构：

[1] Loyola Univ, Dept Chem, New Orleans, LA 70118 USA

[2] USN, Res Lab, Ctr Biomol Sci & Engn, Washington, DC 20375 USA

来源：

SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 05期

关键词：

water-soluble phosphine; aqueous phase catalysis; allylic isomerization;

D O I：

10.1081/SCC-120016328

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A water-soluble rhodium bis-phosphine complex was used for the aqueous phase isomerization of three allylic alcohols. For the isomerization of cinnamyl alcohol, the-catalyst was recycled with slight loss of activity and the optimum phosphine:rhodium ratio was found to be 6:1.

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页码：827 / 831

页数：5

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