Synthesis and characterization of a dimeric complex of Cu-II with thiosalicylic acid and pyridine

被引：23

作者：

Ferrer, EG ^{[1
]}

Williams, PAM ^{[1
]}

机构：

[1] NATL UNIV LA PLATA,FAC CIENCIAS EXACTAS,CTR QUIM INORGAN CEQUINOR,RA-1900 LA PLATA,ARGENTINA

来源：

POLYHEDRON | 1997年 / 16卷 / 19期

关键词：

copper(II); thiosalicylic acid; structure; spectroscopic data; thermal behavior; magnetic measurements; COPPER(II);

D O I：

10.1016/S0277-5387(97)00081-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction between the Cu2+ cation and thiosalicylic acid was investigated. The solid complex is formed in methanolic solution and contains two Cu-II ions bridged by carboxylate groups of four ligand molecules and pyridine ligands that occupy the sixth coordination positions. Spectral measurements (IR, Raman and electronic spectra) show the lack of interaction of the -SH group in coordination. These results are supported by elemental and thermogravimetric analysis as well as magnetochemical measurements. (C) 1997 Elsevier Science Ltd.

引用

页码：3323 / 3325

页数：3

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