Principles and implementations of dissipative (dynamic) self-assembly

被引:257
作者
Fialkowski, M
Bishop, KJM
Klajn, R
Smoukov, SK
Campbell, CJ
Grzybowski, BA
机构
[1] Northwestern Univ, Dept Chem & Biol Sci, Evanston, IL 60208 USA
[2] Northwestern Univ, NW Inst Complex Syst, Evanston, IL 60208 USA
关键词
D O I
10.1021/jp054153q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dynamic self-assembly (DySA) processes occurring outside of thermodynamic equilibrium underlie many forms of adaptive and intelligent behaviors in natural systems. Relatively little, however, is known about the principles that govern DySA and the ways in which it can be extended to artificial ensembles. This article discusses recent advances in both the theory and the practice of nonequilibrium self-assembly. It is argued that a union of ideas from thermodynamics and dynamic systems' theory can provide a general description of DySA. In parallel, heuristic design rules can be used to construct DySA systems of increasing complexities based on a variety of suitable interactions/potentials on length scales from nanoscopic to macroscopic. Applications of these rules to magnetohydrodynamic DySA are also discussed.
引用
收藏
页码:2482 / 2496
页数:15
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