Bromo[tris(2-cyanoethyl)phosphine]gold(I), [(CEP)AuBr]

被引：9

作者：

AlArfaj, AR

Hussain, MS

Isab, AA

Akhtar, MN

机构：

[1] Department of Chemistry, King Fahd Univ. Petrol. and Minerals, KFUPM Box 1830

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195009814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In [AuBr(C9H12N3P)], two C=N groups of the tris(2-cyanoethyl)phosphine (CEP) ligand are positioned in the vicinity of square-planar coordination sites so as to shield the central Au-I atom in at least two directions. Although the disposition of two of the C=N groups is indicative of Au ... C=N interactions, these groups do not participate in the metal coordination. The observed shielding of the metal atom is similar to that reported for one of the polymorphs of the monomeric complex [(CEP)AuCl].

引用

页码：550 / 553

页数：4