The first mixed iodide-dithiocarbamate complex of selenium(II):: catena-poly[[(di-n-propyldithiocarbamato-S,S′)selenium(II)]-μ-iodo]

被引：3

作者：

Rajashree, S ^{[1
]}

Kumar, RK

Aravamudan, G

Udupa, MR

Sivakumar, K

Fun, HK

机构：

[1] Indian Inst Technol, Dept Chem, Chennai 600036, India

[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Penang 11800, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199003996

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [SeI(C7H14NS2)](n), was prepared by the oxidative displacement of one of the dithiocarbamates in bis(di-n-propyldithiocarbamato)selenium(II) using iodine. This complex has a polymeric structure, with the central Se atoms bridged by the iodine ions. The geometry around each Se atom is planar trapezoidal (SeS2I2), with Se-I distances of 3.124 (2) and 3.232(1) Angstrom. This is the first example of a mixed iodide-dithiocarbamate complex of selenium(II).

引用

页码：1320 / 1322

页数：3

共 11 条

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