A vibrational spectroscopic study of endohedral Li@C-60 fullerenes

被引：16

作者：

Jantoljak, H ^{[1
]}

Krawez, N ^{[1
]}

Loa, I ^{[1
]}

Tellgmann, R ^{[1
]}

Campbell, EEB ^{[1
]}

Litvinchuk, AP ^{[1
]}

Thomsen, C ^{[1
]}

机构：

[1] MAX BORN INST NICHTLINEARE OPT & KURZZEITSPEKTROS,D-12474 BERLIN,GERMANY

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1997年 / 200卷

关键词：

endohedral fullerenes; Raman spectroscopy; infrared spectroscopy;

D O I：

10.1524/zpch.1997.200.Part_1_2.157

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report on Raman and Fourier-transform infrared spectroscopy studies on lithium-implanted fullerene films containing endohedral Li@C-60. The measurements were performed as a function of temperature, polarization and time. They exhibit some significant differences compared to the pristine material: a broad band in the range 300-500 cm(-1) where the vibrational and rotational modes of endohedral Li were predicted, a strong broadening of the internal modes, a lineshift of the A(g)(1) and A(g)(2) modes and a change in the relative intensities and the depolarization ratios. A striking result is the temporal change in the spectra on the time scale of a few weeks.

引用

页码：157 / 164

页数：8

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