Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds

被引：133

作者：

Díez-González, S ^{[1
]}

Scott, NM ^{[1
]}

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 09期

关键词：

D O I：

10.1021/om0600487

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel cationic copper complexes bearing two N-heterocyclic carbenes (NHCs) have been synthesized and fully characterized. These air- and moisture-stable complexes were found to be highly active toward the hydrosilylation of ketones with varying steric congestion, aldehydes (even enolizable ones), and esters.

引用

页码：2355 / 2358

页数：4

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