Crystal-to-crystal phase transition in self-assembled mesoporous iron oxide films

被引:85
作者
Brezesinski, T [1 ]
Groenewolt, M [1 ]
Antonietti, M [1 ]
Smarsly, B [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
关键词
electron microscopy; iron oxide; mesoporous materials; phase transitions; self-assembly;
D O I
10.1002/anie.200502332
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Keeping order: Mesoporous crystalline iron oxide thin films were prepared by using special block copolymer templates. The optimized templating properties and temperature stability of the porogens allowed a crystal-to-crystal phase transition (from goethite to hematite) within the walls of the porous scaffold without disruption of the mesostructure. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:781 / 784
页数:4
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