Synthesis and catalytic applications of soluble polymer-supported BINOL

被引：67

作者：

Jayaprakash, D ^{[1
]}

Sasai, H ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 18期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/S0957-4166(01)00443-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a soluble polymer containing BINOL residues is described. Titanium-BINO Late and AlLibis(binaphthoxide) catalysts are easily generated from this polymer and applied to the asymmetric reaction of Et2Zn with benzaldehyde and the asymmetric Michael addition. respectively. The products are obtained in good yields with high enantioselectivities. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2589 / 2595

页数：7

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