Metal-oxo cluster-supported transition metal complexes:: hydrothermal synthesis and characterization of [{M(phen)2}2(Mo8O26)] (M = Ni or Co)

被引：148

作者：

Xu, JQ ^{[1
]}

Wang, RZ

Yang, GY

Xing, YH

Li, DM

Bu, WM

Ye, L

Fan, YG

Yang, GD

Xing, Y

Lin, YH

Jia, HQ

机构：

[1] Jilin Univ, Dept Chem, Changchun 130023, Jilin, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[3] Jilin Univ, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China

[4] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 11期

关键词：

D O I：

10.1039/a900643e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new metal-ore supported transition metal complexes, E{M(phen)(2)}(2)(Mo8O26) (M = Ni or CO; phen = 1,10-phenanthroline) are synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the octamolybdate possesses a novel unprecedented structure and that [M(phen)(2)](2+) units are covalently bonded to the [Mo8O26](4-) cluster.

引用

页码：983 / 984

页数：2

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