Hydrodynamics and mass transfer of the coaxial jet mixer in flow injection analysis

被引:14
作者
Andreev, VP
Koleshko, SB
Holman, DA
Scampavia, LD
Christian, GD
机构
[1] Russian Acad Sci, Inst Analyt Instrumentat, St Petersburg, Russia
[2] St Petersburg State Tech Univ, Dept Hydrodynam, St Petersburg 195251, Russia
[3] Univ Washington, Dept Chem, Seattle, WA 98195 USA
关键词
D O I
10.1021/ac981037t
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A coaxial jet mixer that was previously proposed for rapid and efficient mixing under laminar now conditions has been studied both theoretically and experimentally. ia mathematical model that consists of a set of Navie-Stokes equations that determine the now velocities and three diffusion-convection reaction equations that determine the reactant and product concentrations has been developed. Equations are solved with the help of finite difference techniques for different now conditions. The quality of sample and reagent mixing is characterized by the mean product concentration and the amount of product produced. Theoretical results are compared with experimental ones for the mixing of bromothymol blue (a pH indicator) in the outer capillary with NaOH in the inner capillary of the jet mixer.
引用
收藏
页码:2199 / 2204
页数:6
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