Computer-aided design and experimental application of a novel electrochemical cell: The confluence reactor

被引:18
作者
Fulian, Q [1 ]
Stevens, NPC [1 ]
Fisher, AC [1 ]
机构
[1] Univ Bath, Sch Chem, Bath BA2 7AY, Avon, England
关键词
D O I
10.1021/jp9805003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new electrochemical device is reported based on the confluence of two streams of solution. This confluence reactor was designed using finite element simulations to establish the cell geometry and solution velocities appropriate to maintain well-defined hydrodynamic conditions. Computational data is presented to illustrate the flexibility of the tool for the investigation of chemical reaction mechanisms. Experimental studies are presented which examine the relationship between reactant solution velocities and electrolysis current. Excellent agreement is noted between the computational predictions and experimental results. The confluence reactor is shown to be an easy-to-construct, cheap, and simple tool that will offer significant benefits to the exploration of chemical and electrochemical processes. The potential applications of the reactor are noted.
引用
收藏
页码:3779 / 3783
页数:5
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