Indolynes as Electrophilic Indole Surrogates: Fundamental Reactivity and Synthetic Applications

被引：77

作者：

Bronner, Sarah M. ^{[1
]}

Bahnck, Kevin B. ^{[1
]}

Garg, Neil K. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 04期

关键词：

PAR SUBSTITUTION ARYNIQUE; DIRECTED ORTHO-METALATION; ARYNES; CYCLOADDITION; COMPLEXES; CHEMISTRY; ARYLATION; HETARYNES; SKELETON; BENZYNE;

D O I：

10.1021/ol802958a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild method to access a variety of substituted indole derivatives has been developed. The strategy relies on the generation of highly reactive indolyne intermediates, which function as electrophilic indole surrogates.

引用

页码：1007 / 1010

页数：4

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