Electrochemical behavior of an Ag/TiO2 composite surfaces

被引：37

作者：

Boskovic, I

Mentus, SV

Pjescic, M

机构：

[1] Univ Belgrade, Fac Phys Chem, Belgrade 11000, Serbia Monteneg

[2] Podgorica Univ, Fac Technol & Met, Podgorica 81000, Serbia Monteneg

来源：

ELECTROCHIMICA ACTA | 2006年 / 51卷 / 14期

关键词：

composite electrocatalysts; oxygen reduction reaction; rotating disc electrode; silver electrodeposition; titanium dioxide;

D O I：

10.1016/j.electacta.2005.07.054

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Silver in a form of,randomly distributed submicron-sized particles was electrodeposited, and simultaneously, titanium dioxide layer was formed, on the surface of mechanically polished titanium, by its potentiodynamic polarization in an aqueous AgNO3 solution. In such obtained Ag/TiO2 composite layer, the particle size distribution, and silver loading were determined by means of scanning electron microscopy. The electrochemical response of this composite layer was studied in both oxygen-free and oxygen saturated aqueous 0.1 M NaOH solution. The catalytic activity toward oxygen reduction reaction of this and other forms of silver- and platinum-based materials was compared. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：2793 / 2799

页数：7

共 61 条

[21] Colloidal nano-particles of semiconductors and metals: Electronic structure and processes [J].