Synthesis of fluorous azodicarboxylates: towards cleaner Mitsunobu reactions

被引：49

作者：

Dobbs, AP ^{[1
]}

McGregor-Johnson, C ^{[1
]}

机构：

[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(02)00322-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a fluorous analogue of diethyl azodicarboxylate (DEAD) is described and preliminary results for its use in the Mitsunobu reaction given. Use of fluorous extraction methods have shown that chromatography is not necessary for reaction purification. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：2807 / 2810

页数：4

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