Homogeneous and heterogeneous dehydrogenation reactions of cyclooctane with palladium(II) complexes as catalysts

被引：11

作者：

Taubmann, Sandra ^{[1
]}

Alt, Helmut G. ^{[1
]}

机构：

[1] Univ Bayreuth, Anorgan Chem Lab, D-95440 Bayreuth, Germany

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 289卷 / 1-2期

关键词：

CH bond activation; homogeneous catalyst; heterogeneous catalyst; dehydrogenation; palladium complexes;

D O I：

10.1016/j.molcata.2008.04.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of new palladium(II) complexes with heteroatomic chelating ligands (carboxylates and alcoholates) was synthesized. The catalytic activities of the palladium complexes were successfully tested for catalytic CH-activation reactions of cyclooctane. They gave TONs of 2.6-26.5 (300 degrees C, 16 h) in homogeneous solution and 4.6-21.4 (400 degrees C, 5 h) in heterogeneous reactions. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：44 / 48

页数：5

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