Titanium complexes of chelating dianionic amine bis(phenolate) ligands: an extra donor makes a big difference

被引：95

作者：

Tshuva, EY

Versano, M

Goldberg, I

Kol, M ^{[1
]}

Weitman, H

Goldschmidt, Z

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 08期

基金：

以色列科学基金会;

关键词：

phenolate ligands; titanium complexes; octahedral geometry; crystal structures;

D O I：

10.1016/S1387-7003(99)00096-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two dianionic amine bis(phenolate) ligands are introduced and their reactions with titanium tetra( iso-propoxide) studied; ligand I having a single N-donor group leads exclusively to a homoleptic Lig(2)Ti type complex whereas ligand 3 having an additional N-donor on a side arm leads exclusively to a LigTi(OPri)(2) type complex. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：371 / 373

页数：3

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