Hexaphyrin Fused to Two Anthracenes

被引：32

作者：

Naoda, Koji ^{[4
]}

Mori, Hirotaka ^{[4
]}

Aratani, Naoki ^{[3
,4
]}

Lee, Byung Sun ^{[1
,2
]}

Kim, Dongho ^{[1
,2
]}

Osuka, Atsuhiro ^{[4
]}

机构：

[1] Yonsei Univ, Spect Lab Funct Elect Syst, Seoul 120749, South Korea

[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

[3] PRESTO Japan Sci & Technol Agcy, Tokyo, Japan

[4] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 39期

关键词：

anthracene; conjugation; hexaphyrin; porphyrinoids; two-photon absorption; EXPANDED PORPHYRINS; 2-PHOTON ABSORPTION; MOLECULAR WIRES; ELECTROCHEMICAL PROPERTIES; ELECTRONIC COMMUNICATION; AROMATICITY; DIPORPHYRINS; CONJUGATION; OXIDATION; CREATION;

D O I：

10.1002/anie.201204446

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gold standard: A bis(Au III) complex containing the title compound was prepared and characterized (see scheme; DDQ=2,3-dichloro-5,6- dicyano-1,4-benzoquinone, Tf=trifluoromethanesulfonyl). Owing to the effective conjugative network over the flat and elongated rectangular molecular frame, this complex displays a remarkably red-shifted and sharp Q-band-like band at 1467 nm, multiple reversible redox potentials, and a large TPA cross-section value. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9856 / 9859

页数：4

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