Synthesis of 2-fluoro- acids, esters, and amides from alpha-dicyanoepoxides

被引：7

作者：

Amanetoullah, AO

Chaabouni, MM

Baklouti, A

机构：

[1] FAC SCI TUNIS,LAB CHIM STRUCT ORGAN,TUNIS 1060,TUNISIA

[2] ECOLE SUPER IND ALIMENTAIRES,TUNIS 1003,TUNISIA

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 06期

关键词：

D O I：

10.1080/00397919608003723

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The opening of alpha-dicyanoepoxides by pyridine polyhdrofluoride yields polymerisable 2-fluorocyanoformyls which may be kept intact when diluated in dichloromethane or ether. These intermediates react with nuclecophiles such as water, methanol or amines to give respectivly 2-fluoroacids, esters or amides.

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收藏

页码：1155 / 1161

页数：7

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