Facile Deposition of Multicolored Electrochromic Metal-Organic Framework Thin Films

被引：278

作者：

Wade, Casey R. ^{[1
]}

Li, Minyuan ^{[1
]}

Dinca, Mircea ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 50期

关键词：

electrochemistry; electrochromic materials; metal-organic frameworks; naphthalene diimide; thin films; COLORATION EFFICIENCY MEASUREMENTS; NAPHTHALENE DIIMIDES; REDOX PROPERTIES; CHARGE-TRANSFER; TUNGSTEN-OXIDE; CHEMISTRY; DEVICES; COORDINATION; REDUCTION; BISIMIDES;

D O I：

10.1002/anie.201306162

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks: The solvothermal reaction of Zn2+ ions and bis- (pyrazolyl)naphthalene diimide readily affords strongly adhering, electroactive metal-organic framework thin films on conductive glass substrates (see picture). Electrochemical cycling of these films followed by insitu UV/Vis spectroscopy reveals striking multicolored electrochromic responses. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：13377 / 13381

页数：5

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