Navigating the Color Palette of Solution-Processable Electrochromic Polymers

被引:424
作者
Amb, Chad M. [1 ]
Dyer, Aubrey L. [1 ]
Reynolds, John R. [1 ]
机构
[1] Univ Florida, George & Josephine Butler Polymer Res Lab, Dept Chem, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA
关键词
LIGHT-EMITTING-DIODES; DONOR-ACCEPTOR POLYMER; HIGH-CONTRAST RATIO; EFFICIENCY MEASUREMENTS; CONDUCTING POLYMERS; CONJUGATED POLYMERS; OPTICAL ATTENUATOR; POLYANILINE; DEVICES; GREEN;
D O I
10.1021/cm1021245
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Solution-processable electrochromic (EC) polymers that can be switched from one distinct color state to a highly transmissive and near colorless state are required for applications in both EC windows and displays. Using a tour around the color wheel, we describe the various EC polymer (ECP) compositions that now make a full palette of colors available demonstrating a set of structure-property relationships. Electrochemical and electrochromic characterization methodologies are described and their application to ECPs demonstrated. Processing and patterning methods including spray casting, screen-, flexo-, and ink jet printing, along with photo- and soft lithography are described. Absorptive/transmissive (window type) and absorptive/reflective (display type) devices are described as platforms for practical applications.
引用
收藏
页码:397 / 415
页数:19
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