Movement and diffusion of paramagnetic ions in a magnetic field

被引:30
作者
Fujiwara, M. [1 ]
Mitsuda, K. [1 ]
Tanimoto, Y. [1 ]
机构
[1] Hiroshima Univ, Grad Sch Sci, Higashihiroshima 7398526, Japan
关键词
D O I
10.1021/jp061482p
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The magnetic movement and thermal diffusion have been studied for Cu2+ ions in solution. The Cu2+ ion solution was spotted on the silica gel support and exposed to the magnetic field of 410 kOe(2) cm(-1) intensity x gradient. The Cu2+ ions were attracted toward the filed center. The moving distance and diffusing distance were observed at various time intervals. It is shown that the Cu2+ ions move in a large group composed of Cu2+ ions and H2O molecules. The size of the group is approximately estimated to be of 4.6 mu m diameter by the analysis of the drift velocity of the group and the Cu2+ ion concentration in the group.
引用
收藏
页码:13965 / 13969
页数:5
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