A matrix isolation and DFT study of the generation and characterization of monomeric vapour phase platinum chlorides

被引：17

作者：

Bridgeman, AJ

Cavigliasso, G

Harris, N

Young, NA ^{[1
]}

机构：

[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 351卷 / 3-4期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0009-2614(01)01369-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular platinum monochloride (PtCl) and platinum dichloride (PtCl2) have been prepared from platinum atoms and chlorine doped argon in a hollow-cathode sputtering device, matrix isolated in solid argon and characterized using electronic, infrared and X-ray absorption spectroscopies together with high level DFT calculations. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：319 / 326

页数：8

相关论文

共 33 条

[1] Hybridization peaks in Pt-Cl XANES [J].

Ankudinov, AL ;

Rehr, JJ ;

Bare, SR .

CHEMICAL PHYSICS LETTERS, 2000, 316 (5-6) :495-500

[2] Geometry and hydration structure of Pt(II) square planar complexes [Pt(H2O)4]2+ and [PtCl4]2- as studied by X-ray absorption spectroscopies and quantum-mechanical computations [J].

Ayala, R ;

Marcos, ES ;

Díaz-Moreno, S ;

Solé, VA ;

Muñoz-Páez, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (31) :7588-7593

[3] CALCULATION OF VIBRATIONAL FREQUENCIES OF POLYATOMIC MOLECULES, INCLUDING THOSE OF CRYSTALS [J].

BEATTIE, IR ;

CHEETHAM, N ;

GARDNER, M ;

ROGERS, DE .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (13) :2240-&

[4] THE INTERACTION OF SOME METAL DICHLORIDES (CA, CR, MN, FE, CO, NI, ZN) WITH DINITROGEN [J].

BEATTIE, IR ;

JONES, PJ ;

YOUNG, NA .

CHEMICAL PHYSICS LETTERS, 1991, 177 (06) :579-584

[5] THE INFRARED-SPECTRA OF MATRIX-ISOLATED THORIUM AND URANIUM TETRACHLORIDES - CHANGE OF SHAPE WITH MATRIX GAS [J].

BEATTIE, IR ;

JONES, PJ ;

MILLINGTON, KR ;

WILLSON, AD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (11) :2759-2762

[6]

Binsted N, 1998, EXCURV98 CCLRC DARES

[7]

BINSTED N, 1988, PAXAS PROGRAM ANAL X

[8] On the electronic structures and spectra of NiCl2 and CuCl2 [J].

Bridgeman, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (13) :2601-2607

[9] CORRELATION BETWEEN GASEOUS ATOMIC SPECTRA AND ABSORPTION-SPECTRA OF ATOMS ISOLATED IN NOBLE-GAS MATRICES [J].

CARSTENS, DH ;

BRASHEAR, W ;

ESLINGER, DR ;

GRUEN, DM .

APPLIED SPECTROSCOPY, 1972, 26 (02) :184-+

[10] THE FOURIER-TRANSFORM RAMAN-SPECTRA OF A SERIES OF PLATINUM(II), PALLADIUM(II) AND GOLD(III) SQUARE-PLANAR COMPLEXES [J].

DEGEN, IA ;

ROWLANDS, AJ .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1991, 47 (9-10) :1263-1268

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