A matrix isolation and DFT study of the generation and characterization of monomeric vapour phase platinum chlorides

被引：17

作者：

Bridgeman, AJ

Cavigliasso, G

Harris, N

Young, NA ^{[1
]}

机构：

[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 351卷 / 3-4期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0009-2614(01)01369-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular platinum monochloride (PtCl) and platinum dichloride (PtCl2) have been prepared from platinum atoms and chlorine doped argon in a hollow-cathode sputtering device, matrix isolated in solid argon and characterized using electronic, infrared and X-ray absorption spectroscopies together with high level DFT calculations. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：319 / 326

页数：8

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