Atom transfer radical polymerization of styrene and methyl methacrylate from mesoporous ordered silica particles

被引：82

作者：

Save, M

Granvorka, G

Bernard, J

Charleux, B

Boissière, C

Grosso, D

Sanchez, C

机构：

[1] Univ Paris 06, CNRS, UMR 7610, Lab Chim Polymeres, F-75252 Paris, France

[2] Univ Paris 06, CNRS, UMR 7574, Lab Chim Mat Condensee, F-75252 Paris, France

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 06期

关键词：

atom transfer radical polymerization (ATRP); controlled radical polymerization; grafting from; MSU mesoporous silica; surface-initiated polymerization;

D O I：

10.1002/marc.200500798

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Mesoporous silica was used as Substrate for the grafting of alkyl halides initiators. The control over the surface-initiated polymerization of styrene and MMA, in terms of molar mass and molar mass distribution, was successfully achieved using an ATRP mechanism. The occurrence of the polymerization inside the mesopores was confirmed by thermogravimetric analysis.

引用

收藏

页码：393 / 398

页数：6

相关论文

共 34 条

[1]

Advincula R.C., 2004, POLYMER BRUSHES

[2] ENZYMES AND OTHER PROTEINS ENTRAPPED IN SOL-GEL MATERIALS [J].

AVNIR, D ;

BRAUN, S ;

LEV, O ;

OTTOLENGHI, M .

CHEMISTRY OF MATERIALS, 1994, 6 (10) :1605-1614

[3] Nitroxide-mediated polymerizations from silica nanoparticle surfaces: "Graft from" polymerization of styrene using a triethoxysilyl-terminated alkoxyamine initiator [J].

Bartholome, C ;

Beyou, E ;

Bourgeat-Lami, E ;

Chaumont, P ;

Zydowicz, N .

MACROMOLECULES, 2003, 36 (21) :7946-7952

[4] Nitroxide-mediated polymerization of styrene initiated from the surface of fumed silica. Comparison of two synthetic routes [J].

Bartholome, C ;

Beyou, E ;

Bourgeat-Lami, E ;

Chaumont, P ;

Zydowicz, N .

POLYMER, 2005, 46 (19) :8502-8510

[5] A new synthesis of mesoporous MSU-X silica controlled by a two-step pathway [J].

Boissière, C ;

Larbot, A ;

van der Lee, A ;

Kooyman, PJ ;

Prouzet, E .

CHEMISTRY OF MATERIALS, 2000, 12 (10) :2902-2913

[6] ATRP grafting from silica surface to create first and second generation of grafts [J].

Böttcher, H ;

Hallensleben, ML ;

Nuss, S ;

Wurm, H .

POLYMER BULLETIN, 2000, 44 (02) :223-229

[7] Tethered constrained-geometry catalysts in mesoporous silica: Probing the influence of the "second sphere" on polymer properties [J].

Burkett, SL ;

Soukasene, S ;

Milton, KL ;

Welch, R ;

Little, AJ ;

Kasi, RM ;

Coughlin, EB .

CHEMISTRY OF MATERIALS, 2005, 17 (10) :2716-2723

[8] Atom transfer radical polymerization of n-butyl acrylate from silica nanoparticles [J].

Carrot, G ;

Diamanti, S ;

Manuszak, M ;

Charleux, B ;

Vairon, IP .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (24) :4294-4301

[9] Controlled polymerization in mesoporous silica toward the design of organic-inorganic composite nanoporous materials [J].

Choi, M ;

Kleitz, F ;

Liu, DN ;

Lee, HY ;

Ahn, WS ;

Ryoo, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (06) :1924-1932

[10] Thiocarbonylthio compounds [S=C(Ph)S-R] in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization). Role of the free-radical leaving group (R) [J].

Chong, YK ;

Krstina, J ;

Le, TPT ;

Moad, G ;

Postma, A ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 2003, 36 (07) :2256-2272

← 1 2 3 4 →