Atom transfer radical polymerization of styrene and methyl methacrylate from mesoporous ordered silica particles

被引：82

作者：

Save, M

Granvorka, G

Bernard, J

Charleux, B

Boissière, C

Grosso, D

Sanchez, C

机构：

[1] Univ Paris 06, CNRS, UMR 7610, Lab Chim Polymeres, F-75252 Paris, France

[2] Univ Paris 06, CNRS, UMR 7574, Lab Chim Mat Condensee, F-75252 Paris, France

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 06期

关键词：

atom transfer radical polymerization (ATRP); controlled radical polymerization; grafting from; MSU mesoporous silica; surface-initiated polymerization;

D O I：

10.1002/marc.200500798

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Mesoporous silica was used as Substrate for the grafting of alkyl halides initiators. The control over the surface-initiated polymerization of styrene and MMA, in terms of molar mass and molar mass distribution, was successfully achieved using an ATRP mechanism. The occurrence of the polymerization inside the mesopores was confirmed by thermogravimetric analysis.

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页码：393 / 398

页数：6

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