A facile C-C bond cleavage in the epoxides and its use for the synthesis of oxygenated heterocycles by a ring expansion strategy

被引：21

作者：

Lakshmipathi, P ^{[1
]}

Grée, D ^{[1
]}

Grée, R ^{[1
]}

机构：

[1] Ecole Natl Super Chim Rennes, CNRS, UMR 6052, Lab Synth & Activat Biomol, F-35700 Rennes, France

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 03期

关键词：

D O I：

10.1021/ol017164k

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

The bicyclic epoxy alcohols when treated with DAST gave a new class of rearranged organofluorine compounds, by a ring expansion via C-C bond cleavage of the oxirane ring. The outcome of this reaction with respect to ring size and stereochemical relation between the functionalities is presented here.

引用

页码：451 / 454

页数：4

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