Demonstration of reversible C-C bond cleavage in oxiranylcarbinyl radicals.

被引：10

作者：

Marples, BA ^{[1
]}

Rudderham, JA ^{[1
]}

Slawin, AMZ ^{[1
]}

Edwards, AJ ^{[1
]}

Hird, NW ^{[1
]}

机构：

[1] SMITHKLINE BEECHAM PHARMACEUT, HARLOW CM19 5AW, ESSEX, ENGLAND

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4039(97)00673-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained. (C) 1997 Elsevier Science Ltd.

引用

页码：3599 / 3602

页数：4

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