Octanethiolated Cu and Cu2O nanoparticles as ink to form metallic copper film

被引：23

作者：

Dong, T. -Y. ^{[1
]}

Wu, H. H. ^{[1
]}

Huang, C. ^{[1
]}

Song, J. M. ^{[2
]}

Chen, I. G. ^{[3
]}

Kao, T. H. ^{[3
]}

机构：

[1] Natl Sun Yat Sen Univ, Dept Chem, Ctr Nanosci & Nanotechnol, Kaohsiung 804, Taiwan

[2] Natl Dong Hwa Univ, Dept Mat Sci & Engn, Hualien, Taiwan

[3] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan

来源：

APPLIED SURFACE SCIENCE | 2009年 / 255卷 / 06期

关键词：

Nanoparticle; Monolayer protected cluster; Conductivity; Film; CHEMICAL-VAPOR-DEPOSITION; SELF-ASSEMBLED MONOLAYERS; STABILIZED GOLD CLUSTERS; COLLOIDAL ASSEMBLIES; REVERSE MICELLES; SOLID-STATE; PARTICLES; SIZE; NANOCRYSTALS; EVOLUTION;

D O I：

10.1016/j.apsusc.2008.10.085

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis and spectroscopic characterizations of size-controlled Cu and Cu2O nanoparticles forming self-assembled 2D superlattices with hexagonal packing are described. The scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), and X-ray photoelectron spectroscopy (XPS) were used to characterize the octanethiol-protected copper nanoparticles. Analysis of XPS confirms the formation of oxidized copper nanoparticles. Conductivity of copper metal film (0.1 mm) on the Si wafer can be improved simply by thermal annealing of copper monolayer protected clusters (MPCs) film (4.8 +/- 0.5 x 10(2) mu Omega cm) under air at 300 degrees C for 1 h, and then for another 5 h under a protective atmosphere of 90% N-2-10% H-2. (c) 2008 Elsevier B. V. All rights reserved.

引用

页码：3891 / 3896

页数：6

共 53 条

[1] Direct patterning of copper on polyimide using ion exchangeable surface templates generated by site-selective surface modification [J].

Akamatsu, K ;

Ikeda, S ;

Nawafune, H ;

Yanagimoto, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (35) :10822-10823

[2] Semiconductor clusters, nanocrystals, and quantum dots [J].

Alivisatos, AP .

SCIENCE, 1996, 271 (5251) :933-937

[3] Three-dimensional self-assembled monolayer (3D SAM) of n-alkanethiols on copper nanoclusters [J].

Ang, TP ;

Wee, TSA ;

Chin, WS .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (30) :11001-11010

[4]

Bensebaa F, 1998, SURF SCI, V405, pL472

[5] Gold-sulfur bonding in 2D and 3D self-assembled monolayers: XPS characterization [J].

Bourg, MC ;

Badia, A ;

Lennox, RB .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (28) :6562-6567

[6] SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].

BRUST, M ;

WALKER, M ;

BETHELL, D ;

SCHIFFRIN, DJ ;

WHYMAN, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802

[7] SYNTHESIS AND REACTIONS OF FUNCTIONALIZED GOLD NANOPARTICLES [J].

BRUST, M ;

FINK, J ;

BETHELL, D ;

SCHIFFRIN, DJ ;

KIELY, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1655-1656

[8] Synthesis of Cu nanoparticles and microsized fibers by using carbon nanotubes as a template [J].

Chen, P ;

Wu, X ;

Lin, J ;

Tan, KL .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (22) :4559-4561

[9] Alkanethiolate-protected copper nanoparticles: Spectroscopy, electrochemistry, and solid-state morphological evolution [J].

Chen, SW ;

Sommers, JM .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (37) :8816-8820

[10] Reversible tuning of silver quantum dot monolayers through the metal-insulator transition [J].

Collier, CP ;

Saykally, RJ ;

Shiang, JJ ;

Henrichs, SE ;

Heath, JR .

SCIENCE, 1997, 277 (5334) :1978-1981

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