CuIn1-xAlxSe2 thin films and solar cells

被引:100
作者
Paulson, PD [1 ]
Haimbodi, MW [1 ]
Marsillac, S [1 ]
Birkmire, RW [1 ]
Shafarman, WN [1 ]
机构
[1] Univ Delaware, Inst Energy Convers, Newark, DE 19716 USA
关键词
D O I
10.1063/1.1476966
中图分类号
O59 [应用物理学];
学科分类号
摘要
CuIn1-xAlxSe2 thin films are investigated for their application as the absorber layer material for high efficiency solar cells. Single-phase CuIn1-xAlxSe2 films were deposited by four source elemental evaporation with a composition range of 0less than or equal toxless than or equal to0.6. All these films demonstrate a normalized subband gap transmission >85% with 2 mum film thickness. Band gaps obtained from spectroscopic ellipsometry show an increase with the Al content in the CuIn1-xAlxSe2 film with a bowing parameter of 0.62. The structural properties investigated using x-ray diffraction measurements show a decrease in lattice spacing as the Al content increases. Devices with efficiencies greater than 10% are fabricated on CuIn1-xAlxSe2 material over a wide range of Al composition. The best device demonstrated 11% efficiency, and the open circuit voltage increases to 0.73 V. (C) 2002 American Institute of Physics.
引用
收藏
页码:10153 / 10156
页数:4
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