N,N′-Unsubstituted amidinato metallacycle complexes of Group 13 metal alkyls:: the crystal structure of trimeric [{Me2Al(μ-HNCPhNH)}3]

被引：10

作者：

Barker, J

Aris, DR

Blacker, NC

Errington, W

Phillips, PR

Wallbridge, MGH ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Associated Octel Co Ltd, Dept Chem, S Wirral L65 3HF, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 586卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

Group; 13; amidinato; structure; trimer; metallacycle;

D O I：

10.1016/S0022-328X(99)00253-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The amidinato complexes [Me2ML] (L = HNCPhNH, M = Al, Ga, In; L = (HNCBuNH)-N-t, M = Ga) result from the reaction of the trialkylmetal with an equimolar amount of the amidine. MS data indicate that the complexes exist as dimers or trimers in the gas phase. X-ray crystallographic studies on [(Me2Al(mu-KNCPhNH)}(3)] (1) reveal a novel trimeric structure in the solid state, with bridging benzamidinato ligands, and a 12-membered metallacycle. Reaction of InMe3 with two moles of benzamidine yields a cyclic imidoylamidinato derivative with a six-membered [InNCNCN] ring. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：138 / 144

页数：7

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