Second-order templation: Ordered deposition of supramolecular squares on a chloride-covered Cu(100) surface

被引：62

作者：

Safarowsky, C

Merz, L

Rang, A

Broekmann, P

Hermann, BA

Schalley, CA

机构：

[1] Univ Bonn, Inst Phys & Theoret Chem, D-53115 Bonn, Germany

[2] Univ Basel, Inst Phys, CH-4056 Basel, Switzerland

[3] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 10期

关键词：

adsorption; monolayers; scanning tunnel microscopy; self-organization;

D O I：

10.1002/anie.200352968

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Beneath the surface lies the answer: Metallosupramolecular cations are deposited in an ordered manner on a copper surface, which had previously been covered with chloride ions. The anion layer acts as a second-order template, whose interactions with the cation determine the adsorption process (see scheme).

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页码：1291 / 1294

页数：4

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