Diels-Alder reactions of beta-vinyl-meso-tetraphenylporphyrin with quinones

被引：22

作者：

Faustino, MAF ^{[1
]}

Neves, MGPMS ^{[1
]}

Tomé, AC ^{[1
]}

Silva, AMS ^{[1
]}

Cavaleiro, JAS ^{[1
]}

机构：

[1] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal

来源：

ARKIVOC | 2005年

关键词：

Diels-Alder reactions; cycloadditions; cyclizations; porphyrins; benzoporphyrins; quinones; structural elucidation; NMR;

D O I：

10.3998/ark.5550190.0006.928

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ni(II)-2-vinyl-5,10,15,20-tetraphenylporphyrin reacts with 1,4-naphthoquinone and 1,4-benzoquinone to afford mixtures of rigid porphyrin-quinone derivatives with extended pi-systems. The structures of these novel compounds were deduced from detailed NMR experiments.

引用

收藏

页码：332 / 343

页数：12

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