Synthesis and structure of tetranuclear zinc(II) and binuclear copper(II) complexes of a dithiolate compartmental macrocyclic ligand: A model for the binuclear Cu-A site in cytochrome c oxidase and N2O reductase

被引：57

作者：

Branscombe, NDJ

Blake, AJ

MarinBecerra, A

Li, WS

Parsons, S

RuizRamirez, L

Schroder, M

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

[2] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[3] NATL AUTONOMOUS UNIV MEXICO,FAC QUIM,DEPT QUIM INORGAN,MEXICO CITY 04510,DF,MEXICO

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 22期

关键词：

D O I：

10.1039/cc9960002573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetranuclear cluster [Zn(2)L(mu-OH)](2)[ClO4](2) . 2H(2)O (L = dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylthiophenol) shows two unique dinuclear Zn-II units linked by two Ir-hydroxy bridges; the structure of the Cu-II complex [Cu(2)L(HOMe)(2)](NO3)]PF6 shows square-pyramidal coordination at the Cu centres with two thiolate bridges and two terminal N-donors, with a Cu ... Cu separation of 3.264(2) Angstrom.

引用

收藏

页码：2573 / 2574

页数：2

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